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PinePhone Devs Finally Decide on a Default Distro and it is Manjaro ARM running Plasma Mobile
(www.omgubuntu.co.uk)
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Distributions include the Linux kernel and supporting system software and libraries, many of which are provided by the GNU Project. Many Linux distributions use the word "Linux" in their name, but the Free Software Foundation uses the name GNU/Linux to emphasize the importance of GNU software, causing some controversy.
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I think kde is a great choice for this. It's customizable, it has a solid library of kde apps that have been ported or created for a mobile environment, it has an existing large community and like you said it has kde connect, which could allow for a more unified desktop/mobile experience.