I've been searching for the same thing - a PFA/PFC free shell to go over my regular trousers. I've tried these three and haven't had any luck with any of them:
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Patagonia Torrentshell: I could hardly take a full stride in these, and sizing up was like wearing oversized parachute pants
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Marmot equivalent: Much more mobility, but just not enough for me to pedal on a bike without the pants becoming very taut. I fear they'd rip after a while.
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Outdoor Research equivalent: Satisfactory mobility, but for some reason the ankle cuffs are really wide - water would definitely splash up inside these if you were walking through puddles, so it feels like they miss the mark a little especially considering these are a bit more expensive than the others.
I'm still looking, open to recommendations!